Cu IDHA

INTRODUCTION  OF IDHA CHELATES

The chelating agents are used in a variety of applications including:

★Detergents;

★Agricultural nutrients;

★Industrial cleaners;

★Paper industry;

★Photography.

In agriculture chelated micronutrients prevent, correct and minimize defficiencies, thus increase yields and efficiency of nutrition.

Traditionally, chelating agents are poorly biodegradable, accumulate in the environment and have been detected in surface waters of rivers, lakes, and in soils.

MANUFACTURER INFORMATION

To comply with the rules of green chemistry, PPC Adob in cooperation with LANXESS GmbH has developed the production  process of readily biodegradable chelates (IDHA-brand), which are subject to a joint patent application.

APPLICATION

IDHA chelates are applied in agriculture as:

★Foliar sprays;

★Soil application;  and in horticulture in:

★Hydroponics;

★Fertigation.

CHEMICAL CHARACTERISTICS

From chemical point of view D,L Aspartic acid N-(1,2-dicarboxyethyl) tetrasodium salt is a pentadentate ligand, which forms octahedral structure with metal ions as presented on the figure below

The reaction between the anion IDHAm- and a metal cation Men+ is a reversible one and forms a 1:1 complex.  

IDHAm-+ Men+ = IDHA Me(m-n)-

 KIDHAMe=  [IDHAMe(m-n)-] / [IDHAm][Men-] 

The pK values show that IDHA complexes are of moderate strength, however, enable to apply micronutirents in an available form for the plants.  

MolecularIDHA.

PRODUCTS

In solid form

 
Fe IDHA
Mn IDHA
Zn IDHA
Cu IDHA
Concentration

9.0%

9.0%

10.0%

10.0%

N-NO3

4.5%

4.5%

4.5%

4.5%
pH of 1% water sol.

5.0

9.5

8.0

9.0
pH of 0,1% water sol.

5.5

9.0

8.5

9.5

Conductivity of 1% sol. in mS/cm  at 20℃

6.1

6.2

5.9

6.4
Conductivity of 1%  sol. in mS/cm at 20℃

0.73

0.75

0.70

0.75

In liquid form

 
Fe IDHA
Mn IDHA
Zn IDHA
Cu IDHA
Concentration

3.0%

3.7%

4.6%

4.6%

N-NO3

1.5%

1.6%

1.95%

1.95%
pH

4.2

4.0

6.3

5.7

Conductivity of 1% sol. in mS/cm  at 20℃

3.0

4.4

4.0

4.0
Conductivity of 1%  sol. in mS/cm at 20℃

0.34

0.54

0.48

0.48

Density g/cm3

1.25

1.36

1.33

1.34

OTHER PRODUCTS

PPC ADOB offers also:

★Multicomponent micronutrients based on IDHA chelates;

★Chelated micronutrients in other fertilizers (magnesium nitrate, calcium nitrate, Calmag).

All the above mentioned products are available in both solid and in liquid form. The content of the chelated micronutrients and their concentration can be adjusted to the needs of specific crops.   

BIODEGRADATION OF CHELATES

Characteristics of EDTA and other commercial chelates:

★resistant to decomposition by bacteria, not biodegradable;

★not environment friendly.

The biodegradation tests of FeIDHA:

★carried out according to OECD directive 301E, and OECD 302B. The directives set minimal decomposition levels for readily biodegradable chemicals within 28 days;

★comparison with different commercial iron chelates (EDTA, DTPA, EDDHA).

The biodegradation tests of FeIDHA

The degree of biodegradation is calculated by expressing the concentration of DOC (dissolved organic carbon) removed to the percentage of initially present concentration. Adob’s IDHA chelates can be regarded as readily biodegradable as they decompose acc. To OECD 301C in 78% after 28 days, and acc. To OECD 302E in 89% in 28 days. They may even be described as rapidly biodegradable.  The results have shown that Adob’s IDHA chelate has by far the best biodegradation in comparison with other commercial chelates.

Biodegradation of chelates

Stability at different pH

IDHA chelates were also checked for their stability at different pH.  The amount of Fe IDHA remaining in solution at different pH was studied. The pH of 10-5 M Fe IDHA with 5 ml M Ca Cl2 solution was adjusted with HCl or NaOH.

Samples were placed in a shaker bath for 3,7, or 14 days. After the agitation, chelated Fe was measured by ion pair Chromatography.  The results have shown, that for most pH ranges the Fe remains in solutions after those three periods. Therefore, Adob’s IDHA can be regarded as stable.

Stability at different pH

TESTS
In order to check IDHA efficiency, the chelates have been tested at the following institutions:

★Universidad Autonoma de Madrid – Spain

★Landwirtschaftlische Untersuchungs um Forschungsamt Hannover – Germany

★Akademia Rolnicza Poznan – Poland

★Hebrew University Jerusalem – Israel

★Katholieke Universiteit Leuven – Belgium

IDHA efficiency was tested in comparison with other commercial chelates. Among others the following tests were carried out:

★Soybean in hydroponic

★Chinese cabbage in soil

★Cucumber in hydroponic

The results of selected tests are presented below.

TEST - HYDROPONICS
 The test of FeIDHA on soybean in hydroponics in comparison with other commercial Fe chelates

Soybean is one of the best studied susceptible crop, with low Fe chelate reductase activity. This experiment has been done in a growth chamber.

★ pH was buffered at 7,5 with 0,1 mM Hepes.

★Water was added every two days and the solution was renewed every week

★5 mM Fe was added at the treatments in four replications

The result have proved that Fe IDHAapplication was better than FeEDTA effecting thus in higher yield.

Results soybean test

Results soybean test

Soybean in hydroponics

Soybean in hydroponics
TEST - SOIL
The test of FeIDHA on Chinese cabbage in soil  in comparison with other commercial Fe chelates
Plants were used in a biological experiment.

★Plants were seed and germinated on peat-clay soil in two different pH ranges (5.5-6.0 and 6.5-7.0).

★30 mg of Fe/l of water was added.

After 26 days head of Chinese cabbage were washed, weighted and dried. In the case of the FeIDHA the Fe content in dry leaves is similar to those in which EDDHA and EDTA were used. 

Results Chinese cabbage

Results Chinese cabbage

Chinese cabbage in soil

Chinese cabbage in soil

CONCLUSIONS
★IDHA chelates are an enviroment friendly alternative to conventional complexing agents.

★In June 2001 Bayer was awarded the US President Green Chemistry Challange Award for its product.

★This agent is characterized by excelletnt chelation capabilities, especially for iron-III, manganese-II, zinc-II and coppper-II

★The new micronutrients may even be called rapidly biodegradable, which is very important especially because of  strong criticism of EDTA, and its limited application as chelation agent in many industries.